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Journal Articles

Automation of precise gas control for material-process researches; Application to synchrotron radiation real-time observation of surface reactions

Nakamura, Takafumi*; Yamamoto, Yukio*; Arakawa, Masakazu*; Maruyama, Akio*; Yoshigoe, Akitaka

Sangyo Oyo Kogakukai Rombunshi, 11(2), p.109 - 114, 2023/09

Surface chemistry experimental end-station at BL23SU in SPring-8 is widely used to study various surfaces and interfaces of functional materials by means of soft X-rays synchrotron radiation. To analyze surface chemical reactions between gas and solid surfaces, an accurate control of flow-rates of gases is essential. This paper describes a computerized automatic gas flow control system to improve the accuracy and reproducibility of gas-surface reaction experiments in the pressure range of ultra-high vacuum (molecular flow) conditions. The system uses feedback control to operate the slow-leak valve to control the gas-pressure. As a result, the system achieved results equivalent to those of a skilled experimenter.

Journal Articles

Interface atom mobility and charge transfer effects on CuO and Cu$$_{2}$$O formation on Cu$$_{3}$$Pd(111) and Cu$$_{3}$$Pt(111)

Tsuda, Yasutaka; Gueriba, J. S.*; Makino, Takamasa*; Di$~n$o, W. A.*; Yoshigoe, Akitaka; Okada, Michio*

Scientific Reports (Internet), 11, p.3906_1 - 3906_8, 2021/02

 Times Cited Count:3 Percentile:15.24(Multidisciplinary Sciences)

Journal Articles

Synchrotron radiation photoelectron spectroscopy study on oxides formed at Ge(100)2$$times$$1 surface in atmosphere

Yoshigoe, Akitaka

Japanese Journal of Applied Physics, 59(SM), p.SMMB05_1 - SMMB05_5, 2020/07

 Times Cited Count:0 Percentile:0(Physics, Applied)

This study presents the results on synchrotron radiation photoelectron spectroscopy (SR-XPS) analysis of oxides formed in the air on a well-defined clean Ge(100)2$$times$$1 surface prepared in UHV condition. Owing to high energy-resolution SR-XPS, detailed chemical information on Ge oxidation states at the Ge surface was clarified. The result showed that the water vapor in the atmosphere plays an important role to progress slow oxidation of the Ge surface. We believe that the data obtained in this study is valuable for the basic understanding of the formation mechanisms of native oxides at the Ge surfaces.

Journal Articles

Application of combination between time-resolved synchrotron radiation photoelectron spectroscopy and supersonic oxygen molecular beams to surface reaction dynamics study

Yoshigoe, Akitaka

X-sen Kodenshi Bunkoho, p.271 - 282, 2018/12

Based on the series of author's studies, the author explains the time-resolved synchrotron radiation X-ray photoelectron spectroscopy and supersonic oxygen molecular beam study on the adsorption reaction dynamics of oxygen molecules at the Si single crystal surface in the section 5.10 of the new textbook "X-ray Photoelectron Spectroscopy" (Kodan-sha) edited by Yuji Takakuwa.

Journal Articles

Conference report; 11th International Conference on High-Temperature Materials Chemistry (HTMC-11)

Nakamura, Akio

Nihon Genshiryoku Gakkai-Shi, 45(11), p.736 - 737, 2003/11

no abstracts in English

Journal Articles

Initial oxidation states on Si(001) surface induced by translational kinetic energy of O$$_{2}$$ at room temperature studied by Si-2p core-level spectroscopy using synchrotron radiation

Yoshigoe, Akitaka; Teraoka, Yuden

Surface Science, 482-485(Part.1), p.189 - 195, 2001/06

no abstracts in English

JAEA Reports

Specifications for surface reaction analysis apparatus

Teraoka, Yuden; Yoshigoe, Akitaka

JAERI-Tech 2001-006, 91 Pages, 2001/03

JAERI-Tech-2001-006.pdf:3.51MB

no abstracts in English

Journal Articles

Adsorbate-substrate interaction in photofragmentation of trimethylsilylfluoride (Si(CH$$_{3}$$)$$_{3}$$F) physisorbed on Cu(111) following Si K-Shell excitation

Sekiguchi, Tetsuhiro; Baba, Yuji

Surface Science, 433-435, p.849 - 853, 1999/00

 Times Cited Count:14 Percentile:61.12(Chemistry, Physical)

no abstracts in English

Journal Articles

A SIMS study on secondary ion formation during low-enrgy methyl ion beam deposition

*; Aoki, Yasushi; Nagai, Shiro

Nuclear Instruments and Methods in Physics Research B, 108, p.75 - 80, 1996/00

 Times Cited Count:2 Percentile:31.89(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Endowment with the wettability on the surface of tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer by excimer laser irradiation

*; *; Shimizu, Yuichi; Sugimoto, Shunichi*; Nishii, Masanobu; Kawanishi, Shunichi

Chemistry Letters, 1993, p.1637 - 1638, 1993/00

no abstracts in English

Journal Articles

XPS study of Si bombarded with low-energy reactive ions

Yamamoto, Hiroyuki; Baba, Yuji; Sasaki, Teikichi

Nuclear Instruments and Methods in Physics Research B, 73, p.587 - 589, 1993/00

no abstracts in English

Journal Articles

XPS study of Si(100) bombarded with low-energy reactive ions

Yamamoto, Hiroyuki; Baba, Yuji; Sasaki, Teikichi

Hyomen Kagaku, 13(5), p.310 - 313, 1992/07

no abstracts in English

Journal Articles

Excimer laser irradiation effects on fluoropolymer and aromatic polymer

Kawanishi, Shunichi; Sugimoto, Shunichi; Shimizu, Yuichi; Suzuki, Nobutake

J. Photopolym. Sci. Technol., 5(2), p.271 - 278, 1992/00

no abstracts in English

Journal Articles

Surface chemical reactions of Al induced by low-energy D$$_{2+}$$, N$$_{2+}$$, CO$$^{+}$$, and CO$$_{2+}$$ ion bombardment

Nagai, Shiro

Nuclear Instruments and Methods in Physics Research B, 59-60, p.936 - 939, 1991/00

 Times Cited Count:3 Percentile:50.31(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Surface phenomena and their characterization under the low-energy ion irradiation

Yamamoto, Hiroyuki

Kagaku To Kogyo, 43(3), p.377 - 378, 1990/03

no abstracts in English

Journal Articles

Change in tritium-sorption property of stainless steel by thermal surface oxidation

Hirabayashi, Takakuni; K.W.Sung*; Sasaki, Teikichi; Saeki, Masakatsu

Journal of Nuclear Materials, 175, p.78 - 83, 1990/00

 Times Cited Count:9 Percentile:67.09(Materials Science, Multidisciplinary)

no abstracts in English

Oral presentation

Study on chemical reactions at materials surfaces via hyperthermal molecular beams

Teraoka, Yuden

no journal, , 

no abstracts in English

Oral presentation

Synchrotron radiation photoemission electron microscope observation of Cs-containing clay mineral

Yoshigoe, Akitaka; Shiwaku, Hideaki; Kobayashi, Toru; Shimoyama, Iwao; Matsumura, Daiju; Tsuji, Takuya; Nishihata, Yasuo; Yaita, Tsuyoshi; Kogure, Toshihiro*; Motai, Satoko*; et al.

no journal, , 

Fundamental researches on adsorption state of radiaoactive Cs in clay mineral (aluminosilicate) have become important from the virewpoints of development of decontamination or volume-reduction techniques since the accident of Fukushima Daiiichi Nuclear Power Station. Pinpoint surface chemical analysis with nanometer spatial resolutions focusing on a target sample has been needed. In this presentation, I will show our recent work on nanoscale pinpoint surface chemical analysis for Cs-containing clay mineral by means of synchrotron radiation PEEM at BL17SU in SPring-8.

Oral presentation

Hafnium adsorption on clean Si(110)16$$times$$2 single domain surface studied by low energy electron diffraction and electron spectroscopy

Kakiuchi, Takuhiro*; Katsuragi, Takuma*; Nakano, Yuji*; Yoshigoe, Akitaka; Nagaoka, Shinichi*; Mase, Kazuhiko*

no journal, , 

HfO$$_{2}$$ has been becoming important as a future dielectric material for future metal-oxide-semiconductor devices. In this study, surface structure, surface chemical state, and valence electronic structure after oxidation of single domain Si(110)-16$$times$$2 surface have precisely measured by using low-energy-electron diffraction and synchrotron radiation photroemission spectroscopy. It was found that five possible adsorption sites (SC1-SC5) of the single domain Si(110)-16$$times$$2 surface are uniformely reacted with Hf atoms with increasing its exposure, indicating that random Hf adsorption takes place on the surface.

Oral presentation

In situ observations of surface chemical reactions using soft X-ray synchrotron radiation photoelectron spectroscopy

Yoshigoe, Akitaka

no journal, , 

The lecture concerning the utilization of surface chemistry end-station at BL23SU in SPring-8 will be held as part of the Nanotechnology Platform Japan program of MEXT for the year 2016.

23 (Records 1-20 displayed on this page)